Phospholide
WebAug 29, 2005 · The reaction of the bulky phospholide salt Li(2,5- tBu 2 PC 4 H 2)⋅2 THF (1; THF=tetrahydrofuran) with [NiCp*(acac)] (HCp*=pentamethylcyclopentadiene, Hacac=acetylacetone) gives the green air-sensitive phosphanickelocene [NiCp*(2,5-tBu 2 PC 4 H 2)] (2) in yields of about 85 %.An X-ray structural determination of 2 shows long Ni … WebAug 30, 2024 · Here we show that a per-alkylated phospholide, TMP (TMP = {PC 4 Me 4}) allows the one-pot synthesis and isolation of trivalent dibenzyl-ate complexes of the form …
Phospholide
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WebDefinition. Phospholipide (eng: phospholipids) sind Lipide, die über eine Esterbindung mit Phosphorsäure verknüpft sind. Sie sind Hauptbestandteil aller tierischer und pflanzlicher … WebJul 26, 1994 · Several aspects of the chemistry of phospholide and polyphospholide ions under current development are described briefly. They include: the synthesis of flexible tetraphosphorus macrocycles from 2,2′-biphospholide ions; the synthesis of functional phospholide, 1,3- arsaphospholide and 1,2,3-triphospholide ions; the description of new …
WebJan 24, 2024 · Phospholyl(borane) amino acids are easy to store and can be subjected to direct transformation into the corresponding free phospholyl, gold complex, oxide or sulfur derivatives as well as phospholinium salts, thus offering a variety of side chains.
WebApr 17, 2024 · The 1,2-diaza-4-phospholide (dp −) dipotassium ate complexes of chromium(II) {[(η 1-N-3,5-tBu 2 dp) 4 Cr][(η 5-(N,N,C,C,P)) 2-K(η 1-O-THF) 2] 2} (5) and {[(η … WebNov 10, 2010 · ChemInform Abstract: Simple Access to α-Functional Phospholide Ions. Part 2. Application to the Synthesis of 1Methyl2-pyrrolyl and 2- (Diphenylphosphino)phenyl Derivatives Authors: S. HOLAND N....
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WebPhospholes are an important class of five-membered unsaturated phosphorus heterocycles. The substantial enhancement of phosphole chemistry in the last few decades is mainly due to their numerous applications in organic electronics, catalysis and other … symfony quick startWebAttachment of one or two phosphonio substituents converts a phospholide anion not only into a zwitterion or cation but induces as well a redistribution of the π-electrons in the … symfony rate limiterWebMar 1, 2005 · The synthesis of porphyrin-like arrays based on the phosphole ring has moved a step closer with the simple and general route to α-functional phospholide ions presented here [Eq.(a)]. py = 2 ... th-75jx950 hddThe behavior of the secondary phospholes, those with P−H bond, is dominated by the reactivity of this group. The parent phosphole readily rearranges by migration of H from P to carbon-2, followed by dimerization. Most phospholes are tertiary, typically P-methyl or P-phenyl. The nonaromaticity of these phospholes is manifested in their reactivity but the P−C bonds remain intact. For example, they u… th-75jx950 vieraWebA novel reaction mode of phosphametallocenes was discovered. The phospharuthenocenes with cyclohexyl substituents at the α-positions of the η5-phospholide(s) reacted with acyl electrophiles by an initial electrophilic attack to the ruthenium to produce the μ-alkenylidene species with activation of the acyl C═O double bond and elimination of an α-hydrogen. th-75lx700wWebDec 20, 2024 · Their structures showed varied coordination motifs: (i) a dimeric 1,2-diaza-4-phospholide lithium complex with exo-bidentate bridging coordination (4) consists of two … th-75lx700w mobile01Webphospholide anion. Formula: C 4 H 4 P-Molecular weight: 83.0489; Information on this page: Reaction thermochemistry data; References; Notes; Other data available: Gas phase ion … th-75lx950 viera 4k